One-step preparation of vinyl-functionalized material surfaces: a versatile platform for surface modification
Science China Chemistry,
2014,
57,
654-660.
文章链接：http://dx.doi.org/10.1007/s11426-014-5067-1
杜军在Science China Chemistry发表研究论文
发布日期：2014-10-05
A simple approach has been developed to functionalize various substrates, such as gold and polyvinylchloride, with dopamine methacrylamide—a molecule with adhesive properties that mimic those of mussels—to produce a versatile and general platform for subsequent surface modification. With active double bonds on the surface, various polymers, such as poly([2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide (PMEDSAH) and poly(N-vinylpyrrolidone) (PVP), can be grafted by conventional radical polymerization. Double bond surface functionalization and subsequent polymer grafting have been verified by static water contact angle, Fourier transform infrared–attenuated total reflectance (FTIR-ATR) spectroscopy and X-ray photoelectron spectroscopy (XPS) measurements. Protein adsorption assays showed that the polymermodified substrates have good protein-resistant properties. Considering the advantages of facility, versatility and substrateindependence, this method should be useful in designing functional interfaces for bioengineering applications.
